Two-electron wavefunctions for the ground state of alkali negative ions

被引:12
|
作者
Magnier, S
Aubert-Frécon, M
Hanssen, J
Le Sech, C
机构
[1] Inst Phys, Lab Phys Mol & Collis, F-57078 Metz 3, France
[2] CNRS, Lab Spectrometrie Ion & Mol, F-69622 Villeurbanne, France
[3] Univ Lyon 1, UMR 5579, F-69622 Villeurbanne, France
[4] Univ Paris 11, CNRS, Collis Atom & Mol Lab, URA 281, F-91405 Orsay, France
关键词
D O I
10.1088/0953-4075/32/24/301
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Analytic wavefunctions are proposed to determine the energy of the ground state of all alkali negative ions. These functions fulfil the cusp conditions at the singularities of the Coulombic field, and include the correct behaviour for large interparticle separations, They should be useful to determine cross sections of inelastic processes involving two-electron systems as well as to treat interactions between ionic and covalent states in long-range-type models of alkali dimers.
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页码:5639 / 5643
页数:5
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