Synthesis and Properties of a Novel 3D Europium Coordination Polymer with Helical Chain and (3,6)-Connected rtl Net

被引：2

作者：

Liu, Zhifeng ^{[1
]}

Lai, Bowen ^{[2
]}

Wen, Huiliang ^{[1
]}

Robbins, Julianne ^{[3
]}

Huang, Nei ^{[4
]}

机构：

[1] Nanchang Univ, State Key Lab Food Sci & Technol, Nanchang 330047, Jiangxi, Peoples R China

[2] Nanchang Inst Food & Drug Control, Chem Anal Dept, Nanchang 330038, Jiangxi, Peoples R China

[3] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA

[4] Jiangxi Sinograin Qual Supervis Ctr, Nanchang 330000, Jiangxi, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2016年 / 34卷 / 12期

关键词：

europium coordination polymer; helix; topological structure; luminescence; magnetism; METAL-ORGANIC FRAMEWORKS; LUMINESCENT PROPERTIES; TRICARBOXYLATE LIGAND; CRYSTAL-STRUCTURES; ACID; SBUS; ARCHITECTURE; COMPLEXES; CLUSTERS; ZN;

D O I：

10.1002/cjoc.201600466

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first coordination polymer of 2,2'-((4-carboxymethyl-1,3-phenylene)bis(oxy)) diacetic acid (H3L) with europium(III) ion, [Eu(L)(H2O)]center dot 3H(2)O (1), has been hydrothermally synthesized and structurally characterized. Complex 1 exhibits a 3D coordination polymer with helical chain and rtl topology of the point symbol (4.6(2))(2)(4(2).6(10).8(3)) based on [Eu-2(COO)(4)] as secondary building unit (SBU). Furthermore, the luminescent and magnetic properties of complex 1 are studied.

引用

页码：1304 / 1308

页数：5

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