Silica supported Fe3O4 magnetic nanoparticles for magnetic solid-phase extraction and magnetic in-tube solid-phase microextraction: application to organophosphorous compounds

被引：48
|
作者：
Moliner-Martinez, Y. [1 ]
Vitta, Yosmery [2 ]
Prima-Garcia, Helena [3 ]
Gonzalez-Fuenzalida, R. A. [1 ]
Ribera, Antonio [3 ]
Campins-Falco, P. [1 ]
Coronado, Eugenio [3 ]
机构：
[1] Univ Valencia, Fac Quim, Dept Quim Analit, E-46100 Valencia, Spain
[2] Cent Univ Venezuela Paseo Ilustres, Fac Sci, Sch Chem, Urb Valle Abajo 20513, Carracas, Venezuela
[3] Univ Valencia, ICMol, Valencia 46980, Spain
来源：
ANALYTICAL AND BIOANALYTICAL CHEMISTRY | 2014年 / 406卷 / 08期
关键词：
Magnetic nanoparticles; Organophosphorous pesticides; Magnetic solid-phase extraction and magnetic in-tube solid-phase microextraction;
D O I：
10.1007/s00216-013-7379-y
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
This work demonstrates the application of silica supported Fe3O4 nanoparticles as sorbent phase for magnetic solid-phase extraction (MSPE) and magnetic on-line in-tube solid-phase microextraction (Magnetic-IT-SPME) combined with capillary liquid chromatography-diode array detection (CapLC-DAD) to determine organophosphorous compounds (OPs) at trace level. In MSPE, magnetism is used as separation tool while in Magnetic-IT-SPME, the application of an external magnetic field gave rise to a significant improvement of the adsorption of OPs on the sorbent phase. Extraction efficiency, analysis time, reproducibility and sensitivity have been compared. This work showed that Magnetic-IT-SPME can be extended to OPs with successful results in terms of simplicity, speed, extraction efficiency and limit of detection. Finally, wastewater samples were analysed to determine OPs at nanograms per litre.
引用
收藏
页码：2211 / 2215
页数：5
相关论文
共 50 条
  • [1] Silica supported Fe3O4 magnetic nanoparticles for magnetic solid-phase extraction and magnetic in-tube solid-phase microextraction: application to organophosphorous compounds
    Y. Moliner-Martinez
    Yosmery Vitta
    Helena Prima-Garcia
    R. A. González-Fuenzalida
    Antonio Ribera
    P. Campíns-Falcó
    Eugenio Coronado
    Analytical and Bioanalytical Chemistry, 2014, 406 : 2211 - 2215
  • [2] Application of magnetic nanomaterials in magnetic in-tube solid-phase microextraction
    Safari, Meysam
    Yamini, Yadollah
    TALANTA, 2021, 221 (221)
  • [3] Extraction of Genomic DNA Using Magnetic Nanoparticles (Fe3O4) as a Solid-Phase Support
    Saiyed, Z. M.
    Ramchand, C. N.
    AMERICAN JOURNAL OF INFECTIOUS DISEASES, 2007, 3 (04) : 225 - 229
  • [4] Magnetic Nanoparticles for Solid-Phase Extraction
    Gonzalez-Salamo, Javier
    Herrera-Herrera, Antonio V.
    Fanali, Chiara
    Hernandez-Borges, Javier
    LC GC EUROPE, 2016, 29 (04) : 180 - 193
  • [5] MAGNETIC DISPERSIVE SOLID-PHASE EXTRACTION OF CIPROFLOXACIN DRUG AS β-CYCLODEXTRIN FUNCTIONALIZED MAGNETIC NANOTUBES ON Fe3O4 NANOPARTICLES
    Alborji, Arash
    Abniki, Milad
    Moghimi, Ali
    REVUE ROUMAINE DE CHIMIE, 2024, 69 (7-8)
  • [6] Magnetic In-Tube Solid Phase Microextraction
    Moliner-Martinez, Y.
    Prima-Garcia, Helena
    Ribera, Antonio
    Coronado, Eugenio
    Campins-Falco, P.
    ANALYTICAL CHEMISTRY, 2012, 84 (16) : 7233 - 7240
  • [7] Magnetic solid-phase extraction
    Safaríková, M
    Safarík, I
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1999, 194 (1-3) : 108 - 112
  • [8] Magnetic solid-phase extraction
    Šafaříková, Mirka
    Šafařík, Ivo
    Journal of Magnetism and Magnetic Materials, 1999, 194 (01): : 108 - 112
  • [9] Novel Functionalized Polythiophene-Coated Fe3O4 Nanoparticles for Magnetic Solid-Phase Extraction of Phthalates
    Baharin, Siti Nor Atika
    Sarih, Norazilawati Muhamad
    Mohamad, Sharifah
    POLYMERS, 2016, 8 (05)
  • [10] Polyaniline-coated Fe3O4 nanoparticles: An anion exchange magnetic sorbent for solid-phase extraction
    Tahmasebi, Elham
    Yamini, Yadollah
    Mehdinia, Ali
    Rouhi, Fateme
    JOURNAL OF SEPARATION SCIENCE, 2012, 35 (17) : 2256 - 2265
12345