Processing of wet Kinnow mandarin (Citrus reticulata) fruit waste into novel Bronsted acidic ionic liquids and their application in hydrolysis of sucrose

In citrus processing industries, where up to 60% of the whole fruit is discarded, generates citrus waste (peel, seeds, membrane, and pulp) on a massive scale. The waste does not currently have high-value applications, instead the majority is disposed of or pelletized for animal feed. Therefore, a concise and efficacious protocol for processing of Kinnow mandarin (Citrus reticulata) fruit waste to numerous novel Bronsted acidic ionic liquids (3a-k) have been developed. BAILs were characterized using spectroscopic techniques (FT-IR and NMR). Water immiscibility of ILs 3a, 3g and 3h, a property never observed with sulfonic acid ILs, allowed the catalytic application of BAIL 3a in hydrolysis of sucrose/table sugar, giving a mixture of D-glucose and D-fructose in excellent yields. The ionic liquid could be recycled for >3 times without significant loss of activity.