Augmented scaled particle theory for a hard disk fluid

被引:0
|
作者
Qiao, C. Z. [1 ,2 ]
Zhao, S. L. [1 ,2 ,3 ,4 ]
Dong, W. [5 ,6 ]
机构
[1] East China Univ Sci & Technol, State Key Lab Chem Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China
[2] East China Univ Sci & Technol, Sch Chem Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China
[3] Guangxi Univ, Guangxi Key Lab Petrochem Resource Proc & Proc Int, Nanning 530004, Peoples R China
[4] Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China
[5] Ecole Normale Super Lyon, Lab Chim, CNRS, UMR 5182, 46 Allee Italie, F-69364 Lyon 07, France
[6] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chem Biosensing & Chemometr, Changsha 410082, Peoples R China
基金
中国国家自然科学基金;
关键词
Liquid physics; Hard disk fluids; Scaled particle theory; Chemical potential; Surface tension; EQUATION-OF-STATE; IMPROVED PREDICTIONS; THERMODYNAMICS; SPHERES; PROOF;
D O I
10.1016/j.molliq.2022.120507
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The success of scaled particle theory (SPT) can be certainly ascribed to the appealing physical idea embedded in it, i.e., accounting for the work needed to insert a particle into a liquid by a bulk contribu-tion and a surface contribution. So, it can describe bulk and surface thermodynamic properties in the same framework. The surface tension term in SPT involves one flat-surface contribution and two addi-tional contributions due to surface curvatures. High-order curvature terms (also called non-Hadwiger terms) were evidenced. Recently, we have developed an augmented scaled particle theory (ASPT) by add-ing one high-order curvature term for a hard sphere fluid. Here, we extend ASPT to a two-dimensional hard disk fluid. As for the 3D case, our 2D ASPT allows for improving both bulk and surface thermody-namic properties of a hard disk fluid with respect to the original SPT.(c) 2022 Elsevier B.V. All rights reserved.
引用
收藏
页数:11
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