Selective determination of acetone by carbon nanodots based on inner filter effect

被引:11
|
作者
Sai, Liman [1 ]
Wang, Xingyang [1 ]
Chang, Quanhong [1 ]
Shi, Wangzhou [1 ]
Huang, Lei [1 ]
机构
[1] Shanghai Normal Univ, Dept Phys, Guilin Rd 100, Shanghai 200234, Peoples R China
基金
上海市自然科学基金;
关键词
Acetone detection; Fluorescent probe; Inner filter effect; RESONANCE ENERGY-TRANSFER; DEEP-ULTRAVIOLET; QUANTUM DOTS; FLUORESCENCE; NANOPARTICLES; SENSOR; LUMINESCENCE; MELAMINE;
D O I
10.1016/j.saa.2019.03.059
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Fluorescent sensing of acetone has been achieved taking advantage of the unique optical property of acetone. However, the complicated synthesis process of the fluorescent probes limited their application. Here, carbon nanodots (CNDs) derived from glucose were chosen as the sensing material for the first time, which could be obtained by a one-pot microwave-assisted synthesis within 2 min. The CND had ultraviolet excitation spectrum, resulting in an obvious overlap between its excitation band with the absorption band of acetone. The fluorescent quenching occurred via inner filter effect with fast response. The CNDs showed sensitive response to acetone with a detection limit of 0.09 vol%, which was comparable to most previously reported MOF probes. The results of our work indicated the feasibility of IFE-based sensing method, and demonstrated an efficient and convenient way for acetone detection. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页码:290 / 295
页数:6
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