Syntheses, Crystal Structures and Fluorescent Spectra of Two Zn(II) Complexes with Sulfonamide Pyrimidine

被引：0
|
作者：
Zhao Xiu-Hua [1 ]
Zhao Ya-Yun [2 ]
Zhang Jie [2 ]
Pan Jian-Guo [2 ]
Li Xing [1 ,2 ]
机构：
[1] Ningbo Univ, Fac Sci, Ningbo 315211, Zhejiang, Peoples R China
[2] Ningbo Univ, Fac Chem Engn & Mat Sci, Ningbo 315211, Zhejiang, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 30卷 / 03期
关键词：
sulfonamide pyrimidine; Zn(II) complex; crystal structure; fluorescence; METAL-ORGANIC FRAMEWORKS; DERIVATIVES; BEHAVIOR; DRUG;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new Zn(II) compounds, [Zn(L)(2)(bpy)] (1) and {[Zn(L)(2)(bpp)]}(n) (2) (L=sulfonamide pyrimidine, bpy=2,2'-bipyridine, bpp=1,3-bis(4-pyridyl)propane), have been synthesized and characterized by single crystal X-ray diffraction, powder X-ray diffraction (PXRD), thermal analysis, elemental analysis, IR, UV-Vis and fluorescence. Single crystal X-ray analysis reveals that complex 1 is a mononuclear structure and the Zn(I) ion exhibits a tetragonal pyramidal coordination geometry. Complex 2 is a one-dimensional structure and the Zn(II) ion is a tetrahedral coordination geometry. Thermal analyses show that complex 1 and 2 have high thermal stability. CCDC: 935049, 1; 935050, 2.
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页码：633 / 639
页数：7
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