Reactions of carbonyl compounds in basic solutions.: Part 35: The alkaline hydrolysis and reactivity structure spectra correlations of (Z)-4-(substituted benzylidene)-2-phenyl-4H-oxazol-5-ones

被引：0

作者：

Bowden, K

Perjéssy, A ^{[1
]}

Benko, J

Fabian, WMF

Kolehmainen, E

Melikian, GS

Hritzová, O

Laihia, K

Vollárová, O

Taupuzian, VO

Kiriakossian, N

Nissinen, M

机构：

[1] Comenius Univ, Fac Nat Sci, Dept Organ Chem, SK-84215 Bratislava, Slovakia

[2] Comenius Univ, Fac Nat Sci, Dept Chem Phys, SK-84215 Bratislava, Slovakia

[3] Univ Essex, Dept Biol & Chem Sci, Colchester CO4 3SQ, Essex, England

[4] Karl Franzens Univ Graz, Inst Chem, A-8010 Graz, Austria

[5] Univ Jyvaskyla, Dept Chem, FIN-40351 Jyvaskyla, Finland

[6] Yerevan State Univ, Inst Organ Chem, Yerevan 375049, Armenia

[7] Safarik Univ, Fac Nat Sci, Dept Organ Chem, SK-04167 Kosice, Slovakia

[8] NAS Republ Armenia, Inst Fine Organ Chem, Yerevan 375014, Armenia

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 2002年 / 07期

关键词：

carbonyl compounds; basic solutions;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of the alkaline hydrolysis and the configuration, conformation and electronic structure were studied using IR, NMR spectroscopy, X-ray analysis and AMI theoretical calculations for a series of (Z)-4-(substituted benzylidene)-2-phenyl-4H-oxazol-5-ones (1) and compared with analogous results reported for (E)-4-benzylidene-2phenyl-4H-furan-5-ones (5) and related compounds.

引用

页码：309 / 310

页数：2

共 25 条

[1] Base-catalysed hydrolysis and reactivity-spectra correlations of (Z)-4benzylidene-2-(substituted phenyl)oxazol-5(4H)-ones
Palcut, M
Benko, J
Müller, N
Hritzová, O
Vollárová, O
Melikian, GS
JOURNAL OF CHEMICAL RESEARCH-S, 2004, (10): : 649 - 653
[2] Study on the second-order optical behavior of 4-(substituted-benzylidene)-2-phenyl-4H-oxazol-5-one
Song, HC
Wen, H
Li, WM
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2004, 60 (07) : 1587 - 1591
[3] Synthesis of biologically active 4-[1-(4′-hydroxy-2′-oxo-2′H-[1′]-benzopyran-3′-yl) methylidene]-2-phenyl-4H-oxazol-5-ones and imidazol-4-ones
Mulwad, V. V.
Satwe, D. S.
INDIAN JOURNAL OF HETEROCYCLIC CHEMISTRY, 2006, 15 (04) : 327 - 330
[4] Synthesis and study of nonlinear optical properties of 4-substituted benzylidene-2-phenyl oxazol-5-ones by Z-scan technique
Murthy, Y. L. N.
Christopher, V.
Prasad, U. Viplava
Bisht, P. B.
Ramanaih, D. V.
Kalanoor, B. S.
Ali, S. Akbar
SYNTHETIC METALS, 2010, 160 (5-6) : 535 - 539
[5] Reactions of carbonyl compounds in basic solutions. Part 31. The effect of 2-methylsulfonyl, 2-methylsulfinyl and 2-methylsulfanyl substituents on the alkaline hydrolysis of methyl benzoate and phenyl acetate
Bowden, K
Rehman, S
JOURNAL OF CHEMICAL RESEARCH, 1997, (11) : 406 - +
[6] Reactions of carbonyl compounds in basic solutions. Part 30. The effect of 2-formyl,2,6-diformyl and 2-trifluoroacetyl substituents on the alkaline and neutral hydrolysis of methyl benzoate and phenyl acetate
Bowden, K
Izadi, J
Powell, SL
JOURNAL OF CHEMICAL RESEARCH, 1997, (11) : 404 - +
[7] Reactions of carbonyl compounds in basic solutions .22. The mechanisms of the alkaline hydrolysis of methyl cis-3-(substituted benzoyl)-2,3-diphenylacrylates and the 5-methoxy-5-(substituted phenyl)-3,4-diphenylfuran-2(5H)-ones, as well as the ionisation of the corresponding acids
Bowden, K
Byrne, JM
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1997, (01): : 123 - 127
[8] Synthesis of biologically active 4-[1-(2H-[1]-4-hydroxy-2-oxo-benzopyran-3-yl) methylidene]-2-phenyl-4H-oxazol-5-ones and [1,2,4]triazine-6-one and its derivatives
Mulwad, V. V.
Satwe, D. S.
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2006, 45 (05): : 1210 - 1215
[9] REACTIONS OF CARBONYL-COMPOUNDS IN BASIC SOLUTIONS .12. THE MECHANISM OF THE ALKALINE-HYDROLYSIS OF 3-SUBSTITUTED PHENYL 2-ACETYL-BENZOATES AND 2-BENZOYL-BENZOATES
ANVIA, F
BOWDEN, K
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1990, (11): : 1805 - 1807
[10] REACTIONS OF CARBONYL-COMPOUNDS IN BASIC SOLUTIONS .14. THE ALKALINE-HYDROLYSIS OF SUBSTITUTED N-METHYLFORMANILIDES, N-METHYLACETANILIDES, 1-PHENYLAZETIDIN-2-ONES, 1-PHENYL-2-PYRROLIDONES, AND 1-PHENYL-2-PIPERIDONES
BOWDEN, K
BROMLEY, K
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1990, (12): : 2103 - 2109

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