The relationship between dynamics and structure in the far infrared absorption spectrum of liquid water

被引:22
作者
Woods, KN [1 ]
Wiedemann, H
机构
[1] Stanford Univ, BioPhys Program, Stanford, CA 94309 USA
[2] Stanford Univ, Dept Appl Phys, Stanford, CA 94309 USA
[3] Stanford Univ, SSRL, Stanford, CA 94309 USA
关键词
D O I
10.1016/j.cplett.2004.06.013
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Using an intense source of far infrared radiation, the absorption spectrum of liquid water is measured at a temperature ranging from 269 to 323 K. In the infrared spectrum we observe modes that are related to the local structure of liquid water. Here we present a FIR measured spectrum that is sensitive to the low frequency (<100 cm(-1)) microscopic details that exist in liquid water. (C) 2004 Elsevier B.V. All rights reserved.
引用
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页码:159 / 165
页数:7
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