Magnetic Circular Dichroism and Electronic Structure of [Re2X4(PMe3)4]+ (X = Cl, Br)

被引：2

作者：

Habel-Rodriguez, Diana ^{[1
]}

Poineau, Frederic ^{[2
]}

Johnstone, Erik V. ^{[2
]}

Czerwinski, Kenneth R. ^{[2
]}

Sattelberger, Alfred P. ^{[2
,3
]}

Kirk, Martin L. ^{[1
]}

机构：

[1] Univ New Mexico, Dept Chem & Chem Biol, Albuquerque, NM 87131 USA

[2] Univ Nevada, Dept Chem, Las Vegas, NV 89154 USA

[3] Argonne Natl Lab, Energy Engn & Syst Anal Directorate, Lemont, IL 60439 USA

来源：

INORGANIC CHEMISTRY | 2014年 / 53卷 / 03期

基金：

美国国家科学基金会;

关键词：

METAL-METAL BONDS; QUADRUPLE BONDS; SPECTRA; COMPLEXES; ENERGIES; BAND;

D O I：

10.1021/ic4028139

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Magnetic circular dichroism (MCD) and electronic absorption spectroscopies have been used to probe the electronic structure of the classical paramagnetic metal-metal-bonded complexes [Re2X4(PMe3)(4)](+) (X = Cl, Br). A violation of the MCD sum rule is observed that indicates the presence of ground-state contributions to the MCD intensity. The z-polarized delta -> delta* band in the near-IR is formally forbidden in MCD but gains intensity through a combination of ground- and excited-state mechanisms to yield a positive C term.

引用

页码：1260 / 1262

页数：3

共 50 条

[1] Molecular and Electronic Structure of Re2Br4(PMe3)4
Johnstone, Erik V.
Poineau, Frederic
Todorova, Tanya K.
Forster, Paul M.
Sorensen, Lasse K.
Galvan, Ignacio Fdez
Lindh, Roland
Czerwinski, Kenneth R.
Sattelberger, Alfred P.
INORGANIC CHEMISTRY, 2016, 55 (14) : 7111 - 7116
[2] REACTION OF W(CPH)X(CO)2(PME3)2 (X=CL, BR) WITH PME3 TO GIVE W(CPH)X(CO)(PME3)3 - CHARACTERIZATION OF A KETENYLTUNGSTEN INTERMEDIATE
MAYR, A
LEE, TY
KJELSBERG, MA
LEE, KS
ORGANOMETALLICS, 1994, 13 (06) : 2512 - 2515
[3] SYNTHESIS OF MO2X4(PME3)4(MO-4-MO)(X=CL,BR,I) COMPOUNDS BY DECARBONYLATION OF MO2X4(CO)8 AND BY COMPROPORTIONATION OF MO(CO)6 AND MOX3(PME3)3 - X-RAY CRYSTAL-STRUCTURE OF MO2I4(PME3)4.2THF
COTTON, FA
POLI, R
INORGANIC CHEMISTRY, 1987, 26 (19) : 3228 - 3231
[4] Radioactive electron-rich metal-metal triple bonds: the Tc2X4(PMe3)4 complexes (X=Cl, Br)
Sattelberger, Alfred
Poineau, Frederic
Forster, Paul
Todorova, Tanya
Gagliardi, Laura
Czerwinski, Kenneth
NUCLEAR MEDICINE AND BIOLOGY, 2010, 37 (06) : 686 - 686
[5] SPECTROSCOPY AND STRUCTURE OF QUADRUPLY BONDED COMPLEXES UNDER EXTREME PRESSURE (RE2X82-,MO2CL4(PME3)4)
MORRIS, DE
TAIT, CD
DYER, RB
SCHOONOVER, JR
HOPKINS, MD
SATTELBERGER, AP
WOODRUFF, WH
INORGANIC CHEMISTRY, 1990, 29 (18) : 3447 - 3452
[6] Synthesis, structure, and first-principles calculations of [TcBr2(PMe3)4] and [Tc2Br4(PMe3)4] complexes
Poineau, Frederic
Weck, Philippe F.
Forster, Paul M.
Sattelberger, Alfred P.
Czerwinski, Kenneth R.
DALTON TRANSACTIONS, 2009, (46) : 10338 - 10342
[7] Electron self-exchange of Re2X4(PMe2Ph)40/+ (X = Cl, Br) by 1H NMR line broadening in methylene chloride
Coddington, J
Wherland, S
INORGANIC CHEMISTRY, 1997, 36 (27) : 6235 - 6237
[8] Electronic structure and x-ray magnetic circular dichroism in YbAgCu4 and YbInCu4
Antonov, V. N.
Bekenov, L. V.
Antropov, V. P.
PHYSICAL REVIEW B, 2014, 89 (16):
[9] PREPARATION AND PROPERTIES OF THE MO2X4(PME3)4 COMPOUNDS WITH X = NCS AND NCO
COTTON, FA
MATUSZ, M
INORGANIC CHEMISTRY, 1988, 27 (12) : 2127 - 2131
[10] Mixed chloride/phosphine complexes of the dirhenium core -: 4.: Reaction of [Re2Cl8]2- with PMe3:: one more stop on the road to Re2Cl4(PMe3)4
Cotton, FA
Dikarev, EV
Petrukhina, MA
INORGANIC CHEMISTRY COMMUNICATIONS, 1999, 2 (01) : 28 - 30

← 1 2 3 4 5 →