PREDICTION OF LIQUID-LIQUID EQUILIBRIA FOR POLYETHYLENE GLYCOL BASED AQUEOUS TWO-PHASE SYSTEM BY ASOG AND UNIFAC METHOD

被引：8

作者：

Perumalsamy, M. ^{[1
]}

Murugesan, T. ^{[2
]}

机构：

[1] Natl Inst Technol, Dept Chem Engn, Tiruchirappalli 620015, India

[2] Univ Teknol PETRONAS, Chem Engn Programme, Tronoh 31750, Perak, Malaysia

来源：

BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING | 2009年 / 26卷 / 01期

关键词：

Liquid-Liquid equilibria; Polyethylene glycol; Sodium citrate; ASOG; UNIFAC; PHASE-EQUILIBRIA; SODIUM-CITRATE; THERMODYNAMICS; SEPARATION; EXTRACTION; BEHAVIOR; SALTS; WATER;

D O I：

10.1590/S0104-66322009000100016

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Liquid-Liquid equilibrium data were obtained for the polyethylene glycol(2000)(PEG(2000))-sodium citrate-water system at 298.15, 308.15 and 318.15 K. The effect of temperature on binodal and tie line data was studied and published in a previous article (Murugesan and Perumalsamy, 2005). The interaction parameters of ASOG and UNIFAC models were estimated using the LLE data of PEG(2000)-sodium citrate-water system and are used to predict the LLE data for PEG(6000)-sodium citrate-water system at 298.15, 308.15 and 318.15 K (literature data). The predicted LLE data by both ASOG and UNIFAC models showed good agreement with the experimental and literature data.

引用

页码：171 / 180

页数：10

共 50 条

[1] Liquid-liquid equilibria of an aqueous two-phase system containing polyethylene glycol and sodium citrate: experiment and correlation
Zafarani-Moattar, MT
Sadeghi, R
Hamidi, AA
FLUID PHASE EQUILIBRIA, 2004, 219 (02) : 149 - 155
[2] Liquid-liquid equilibria of aqueous two-phase poly(ethylene glycol)-potassium citrate system
Zafarani-Moattar, MT
Hamidi, AA
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2003, 48 (02): : 262 - 265
[3] Liquid-liquid equilibria of aqueous two-phase systems containing polyethylene glycol and sodium succinate or sodium formate
Zafarani-Moattar, MT
Hamzehzadeh, S
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2005, 29 (01): : 1 - 6
[4] Liquid-liquid equilibria of aqueous two-phase systems made of polyethylene glycol and gelatin systems and their application in emulsion formation
Lee, Jia Min
Chan, Eng-Seng
Ramanan, Ramakrishnan Nagasundara
Ooi, Chien Wei
FLUID PHASE EQUILIBRIA, 2020, 508
[5] Modeling of liquid-liquid phase equilibria in aqueous solutions of poly(ethylene glycol) with a UNIFAC-based model
Tritopoulout, EA
Pappa, GD
Voutsas, EC
Economou, IG
Tassios, DP
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (21) : 5399 - 5408
[6] PREDICTION OF LIQUID-LIQUID EQUILIBRIA FOR TERNARY-SYSTEMS BY THE ASOG METHOD
TOCHIGI, K
HIRAGA, M
KOJIMA, K
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1980, 13 (02) : 159 - 162
[7] Prediction of liquid-liquid equilibria of multicomponent fatty systems using the ASOG method
Dantas, Carlos E. S.
Ceriani, Roberta
FLUID PHASE EQUILIBRIA, 2020, 506
[8] Liquid-liquid equilibrium correlation of aqueous two-phase systems composed of polyethylene glycol and nonionic surfactant
Liu, Yang
Wu, Zhongyang
Zhao, Yongjie
THERMOCHIMICA ACTA, 2015, 602 : 78 - 86
[9] Liquid-Liquid Equilibrium of Aqueous Two-Phase Systems Containing Some Synthetic Polyelectrolytes and Polyethylene Glycol
Gruenfelder, Thomas
Pessoa Filho, Pedro A.
Maurer, Gerd
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2009, 54 (02): : 198 - 207
[10] Prediction of liquid-liquid equilibria for PEG 2000-sodium citrate based aqueous two-phase systems
Perumalsamy, Muthiah
Murugesan, Thanapalan
FLUID PHASE EQUILIBRIA, 2006, 244 (01) : 52 - 61

← 1 2 3 4 5 →