Synthesis, vibrational spectra, and structure of 4'-(4aEuro3-benzo-15-crown-5)oxy-2,2':6',2aEuro3-terpyridine (L) and its transition metal complexes. Extraction and ion-selective properties of L

被引：0
|
作者：
Logacheva, N. M. [1 ]
Baulin, V. E. [2 ]
Pyatova, E. N. [3 ]
Ivanova, I. S. [3 ]
Tsivadze, A. Yu. [1 ]
机构：
[1] Russian Acad Sci, AN Frumkin Electrochem Inst, Moscow 117071, Russia
[2] Russian Acad Sci, Inst Physiologically Act Subst, Chernogolovka 142432, Moscow Oblast, Russia
[3] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 35卷 / 09期
基金：
俄罗斯基础研究基金会;
关键词：
CROWN-ETHERS; TERPYRIDINE; CONDUCTANCE; ELECTRODES;
D O I：
10.1134/S1070328409090048
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Complexes of Co(II), Ni(II), Zn(II), and Cu(II) perchlorates and hexafluorophosphates with 4'-(4aEuro(3)-benzo-15-crown-5)oxy-2,2':6',2aEuro(3)-terpyridine (L) [M(L)(2)](ClO4)(2) center dot 3H(2)O and [M(L)(2)](PF6)(2) center dot 2H(2)O were synthesized. The spectral criteria of ligand coordination through the terpyridine nitrogen atoms were established. An assumption concerning the benzo-15-crown-5 conformation in the ligand molecule in the synthesized complexes was made. The extraction and ion-selective properties of L were studied.
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收藏
页码：648 / 656
页数：9
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