Osmotic pressure measurements on strongly interacting polymer colloid dispersions

被引:10
|
作者
Ottewill, RH [1 ]
Parentich, A [1 ]
Richardson, RA [1 ]
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
关键词
osmotic pressure; polymer-colloid dispersions; electrostatic interactions;
D O I
10.1016/S0927-7757(99)00373-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Equipment has been developed for the determination of the osmotic pressure of small-sized particulate dispersions of polystyrene at low volume fractions. The specific conductance of the dispersion and that of a reservoir of salt, in equilibrium with the dispersion separated by a membrane, was measured simultaneously with osmotic pressure. The results are analysed in terms of a low volume fraction theory of osmotic pressure equilibrium between a colloid compartment and salt solution compartment separated by a membrane. (C) 2000 Elsevier Science B.V. All rights reserved.
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页码:231 / 242
页数:12
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