Synthesis, chiral resolution and optical properties of amphiphilic oxa[9] helicene derivatives

被引：10

作者：

Shahabuddin, Mohammad ^{[1
]}

Miah, Md Jalil ^{[2
]}

Iimura, Ken-ichi ^{[1
]}

Kimura, Takao ^{[1
]}

Karikomi, Michinori ^{[1
]}

机构：

[1] Utsunomiya Univ, Grad Sch Engn, Dept Mat & Environm Chem, 7-1-2 Yoto, Utsunomiya, Tochigi 3218585, Japan

[2] Utsunomiya Univ, Grad Sch Engn, Creat Dept Innovat, 7-1-2 Yoto, Utsunomiya, Tochigi 3218585, Japan

来源：

TETRAHEDRON LETTERS | 2017年 / 58卷 / 13期

关键词：

Quinone; Helicene; Chiral HPLC; Circular Dichroism; ONE HUNDRED YEARS; STEREOSELECTIVE SYNTHESES; QUINONE DERIVATIVES; RECOGNITION; CARBOHELICENES; DISCRIMINATION; MOLECULES; CATALYSTS; BINDING; DNA;

D O I：

10.1016/ketlet.2017.02.057

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new class of amphiphilic oxa[9]helicene derivatives were synthesized in excellent-to-fair yields, and successfully characterized by different analytical techniques (e.g., FT-IR, H-1 and C-13 NMR, and HRMS). The compounds were enantiomerically separated by chiral HPLC and the absolute configurations of the enantiomers were confirmed by circular dichroism spectroscopy. Other optical properties (e.g., UV, photoluminescence, specific optical rotation and molecular optical rotation) of the newly synthesized compounds were also examined. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：1334 / 1337

页数：4

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