Ethylene vinyl acetate copolymer: A bio-based cold flow improver for waste cooking oil derived biodiesel blends

被引:35
|
作者
Cao, Leichang [1 ,2 ]
Wang, Jieni [1 ]
Liu, Cheng [1 ]
Chen, Yanwei [1 ]
Liu, Kuojin [1 ]
Han, Sheng [1 ]
机构
[1] Shanghai Inst Technol, Sch Chem & Environm Engn, Shanghai 201418, Peoples R China
[2] Fudan Univ, Dept Environm Sci & Engn, Shanghai 200433, Peoples R China
基金
中国国家自然科学基金;
关键词
Si-based cold flow improver; Waste cooking oil derived biodiesel; Biodiesel-diesel blends; Ethylene vinyl acetate copolymer; LOW-TEMPERATURE PROPERTIES; POUR-POINT; DIESEL; PALM; TRANSESTERIFICATION; JATROPHA; BEHAVIOR;
D O I
10.1016/j.apenergy.2014.06.085
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
This study was conducted to determine the cold flow properties of biodiesel-diesel blends (waste cooking oil derived biodiesel blended with 0# diesel) with ethylene vinyl acetate copolymer (EVAC) as the cold flow improver. The cloud point, cold filter plugging point and pour point of B20 (20 vol.% biodiesel + 80 vol.% 0# diesel) decreased by 8 degrees C, 11 degrees C and 10 degrees C, respectively, after 0.04 wt.% EVAC treatment. The impacts of EVAC on the kinematic viscosity, total glycerol, oxidation stability, acid value and flash point of B20 were also determined. The B20 samples treated with EVAC satisfied ASTM D6751. The crystallization behavior of the blend was investigated via differential scanning calorimetry. The crystallization rate and crystal content of B20 decreased. EVAC is therefore an effective bio-based cold flow improver for biodiesel blends. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:163 / 167
页数:5
相关论文
共 50 条
  • [1] Ethyl acetoacetate: A potential bio-based diluent for improving the cold flow properties of biodiesel from waste cooking oil
    Cao, Leichang
    Wang, Jieni
    Liu, Kuojin
    Han, Sheng
    APPLIED ENERGY, 2014, 114 : 18 - 21
  • [2] Bifunctional additive phenolic acids grafted ethylene-vinyl acetate copolymers for improving the cold flow properties and oxidative stability of waste cooking oil biodiesel-diesel blends
    Sun, Bin
    Zhang, Xiaokang
    Zhao, Yuzhuang
    Chen, Fengfei
    Ren, Feihe
    Lin, Hualin
    Xue, Yuan
    Han, Sheng
    FUEL, 2023, 332
  • [3] Preparation and Evaluation of Modified Ethylene Vinyl Acetate Copolymer as Pour Point Depressant and Flow Improver for Jianghan Crude Oil
    Ren, Yongwen
    Chen, Zhaojun
    Du, Hui
    Fang, Long
    Zhang, Xiaodong
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2017, 56 (39) : 11161 - 11166
  • [4] Improving the cold flow properties of biodiesel from waste cooking oil by ternary blending with bio-based alcohols and diesel from direct coal liquefaction
    Xue, Yuan
    Wang, Lihong
    Lin, Hualin
    Han, Sheng
    Zheng, Shiyou
    JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2021, 98 (09) : 943 - 954
  • [5] Improving the cold flow properties of high-proportional waste cooking oil biodiesel blends with mixed cold flow improvers
    Zhao, Weina
    Xue, Yuan
    Ma, Peng
    Ma, Wenfei
    Wang, Jieni
    Lu, Deli
    Han, Sheng
    RSC ADVANCES, 2016, 6 (16): : 13365 - 13370
  • [6] The Rebirth of Waste Cooking Oil to Novel Bio-based Surfactants
    Qi-Qi Zhang
    Bang-Xin Cai
    Wen-Jie Xu
    Hong-Ze Gang
    Jin-Feng Liu
    Shi-Zhong Yang
    Bo-Zhong Mu
    Scientific Reports, 5
  • [7] The Rebirth of Waste Cooking Oil to Novel Bio-based Surfactants
    Zhang, Qi-Qi
    Cai, Bang-Xin
    Xu, Wen-Jie
    Gang, Hong-Ze
    Liu, Jin-Feng
    Yang, Shi-Zhong
    Mu, Bo-Zhong
    SCIENTIFIC REPORTS, 2015, 5
  • [8] Optimized biodiesel production from waste cooking oil using a functionalized bio-based heterogeneous catalyst
    Amenaghawon, Andrew Nosakhare
    Obahiagbon, Kessington
    Isesele, Victor
    Usman, Fauzan
    CLEANER ENGINEERING AND TECHNOLOGY, 2022, 8
  • [9] Bio-Based Thermosetting Resins from Waste Cooking Oil
    Palucci, Benedetta
    Vignali, Adriano
    Ravasio, Nicoletta
    Zaccheria, Federica
    Bertini, Fabio
    MACROMOLECULAR SYMPOSIA, 2024, 413 (04)
  • [10] Linear and nonlinear viscoelasticity of oleogels based on vegetable oil and ethylene vinyl acetate copolymer/isotactic polypropylene blends
    Martin Alfonso, Jose Enrique
    Valencia, Concepcion
    JOURNAL OF APPLIED POLYMER SCIENCE, 2015, 132 (34)