Cobalt-catalysed hydrovinylation as the key step in a short synthesis of moenocinol

被引:35
|
作者
Hilt, Gerhard [1 ]
Treutwein, Jonas [1 ]
机构
[1] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany
关键词
JULIA-KOCIENSKI OLEFINATION; ALDER-ENE REACTION; STEREOSELECTIVE-SYNTHESIS; DIELS-ALDER; ALKENES; 1,4-HYDROVINYLATION; BIOSYNTHESIS; 1,3-DIENES; SULFONE; ALKYNES;
D O I
10.1039/b822023a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A regio- and chemoselective cobalt(I)-catalysed 1,4-hydrovinylation reaction is the key step in the straightforward and convergent synthesis of moenocinol, the aglycone of moenomycin A.
引用
收藏
页码:1395 / 1397
页数:3
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