Chiral phosphoric acids: Powerful organocatalysts for asymmetric addition reactions to imines

被引：375
|
作者：
Connon, Stephen J. [1 ]
机构：
[1] Univ Dublin Trinity Coll, Dept Chem, Ctr Synth & Chem Biol, Dublin 2, Ireland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 24期
关键词：
amines; asymmetric synthesis; enantioselectivity; organocatalysis; phosphorus;
D O I：
10.1002/anie.200600529
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Loaded with potential: The enormous potential of chiral phosphoric acids (see formulae) as promoters of novel, highly enantioselective addition reactions to imines under mild conditions has recently been recognized. The use of such catalysts has brought about the development of a number of new asymmetric reactions for the synthesis of amine-based chiral building blocks. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：3909 / 3912
页数：4
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