Synthesis of Zn3Nb2O8 ceramics using a simple and effective process

Synthesis of Zn3Nb2O8 ceramics using a simple and effective reaction-sintering process was investigated. The mixture of ZnO and Nb2O5 was pressed and sintered directly without any prior calcination. Single-phase Zn3Nb2O8 ceramics could be obtained. Density of these ceramics increased with soaking time and sintering temperature. A maximum density 5.72 g/cm(3) (99.7% of the theoretical density) was found for pellets sintered at 1170 degrees C for 2 It. Pores were not found and grain sizes >20 mu m were observed in pellets sintered at 1170 degrees C. Abnormal grain growth occurred and grains >50 mu m could be seen in Zn3Nb2O8 ceramics sintered at 1200 degrees C for 2 h and 1200 degrees C for 4 h. Reaction-sintering process is then a simple and effective method to produce Zn3Nb2O8 ceramics for applications in microwave dielectric resonators. (C) 2009 Elsevier Ltd and Techna Group S.r.l. All rights reserved.