Synthesis of Mono-, Di-, and Trinuclear Rhodium Diphosphine Complexes Containing Light-Harvesting Fluorene Backbones

被引：13
|
作者：
Matsusaka, Yuko [1 ]
Shitaya, Shoji [1 ]
Nomura, Kotohiro [1 ]
Inagaki, Akiko [1 ]
机构：
[1] Tokyo Metropolitan Univ, Grad Sch Sci & Engn, 1-1 Minami Osawa, Hachioji, Tokyo 1920397, Japan
来源：
INORGANIC CHEMISTRY | 2017年 / 56卷 / 03期
关键词：
PHOTOCATALYTIC ACTIVITY; ALPHA-METHYLSTYRENE; OXIDATIVE ADDITION; WATER OXIDATION; ACTIVATION; CATALYSIS; CRYSTAL; BONDS;
D O I：
10.1021/acs.inorgchem.6b02423
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Syntheses and structural determination of rhodium complexes ligated by diphosphines containing light-harvesting fluorene backbones are presented. In these rhodium complexes, the rhodium center is surrounded by a light-absorbing diphosphine unit. The presence of Rh-Rh bonding interactions is suggested by density functional theory studies.
引用
收藏
页码：1027 / 1030
页数：4
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