Rheological behavior of poly(m-phenyleneisophthalamide) in ionic liquid

被引：18
|
作者：
Zhao Tingting [1 ]
Wang Huaping [1 ]
Wang Biao [1 ]
Tu Xiaoping [1 ]
Zhang Yumei [1 ]
Jiang Jianming [1 ]
机构：
[1] Donghua Univ, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 200051, Peoples R China
来源：
POLYMER BULLETIN | 2006年 / 57卷 / 03期
关键词：
D O I：
10.1007/s00289-006-0560-0
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The rheological behavior of poly(m-phenyleneisophthalamide) (PMIA) in 1-n-butyl-3-methylimidazolium chloride ([Bmim]Cl, ionic liquid) has been investigated. The polymer in the concentration range investigated exhibits very different behavior between [Bmim]Cl and DMAc/LiCl solvent. Unlike in DMAc/LiCl solvent, PMIA/[Bmim]Cl solution exhibits maxima in apparent viscosity-concentration plots in the range studied. The complex viscosity-frequency behavior of the PMIA/[Bmim]Cl solutions is similar to that steady-state rheological behavior. The different rheological behavior shows the interaction between macromolecule and IL which leading the supermolecular aggregates in PMIA/[Bmim]Cl solution.
引用
收藏
页码：369 / 375
页数：7
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