Synthesis and characterization of carboxylate-bridged copper(II) dinuclear complex

被引：5
|
作者：
Choi, KY [1 ]
Park, SY [1 ]
Shin, AK [1 ]
机构：
[1] Kongju Natl Univ, Dept Chem Educ, Kong Ju 314701, South Korea
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2006年 / 36卷 / 01期
关键词：
crystal structure; bis(2-pyridylmethyl)amino-2-ethanoic acid; dinuclear copper(II) complex; square-pyramidal geometry; antiferromagnetism;
D O I：
10.1007/s10870-005-9008-x
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The dinuclear copper(II) complex {[Cu(pmea)Cl][Cu(H2O)(3)Cl]}(Cl)center dot H2O (1) (pmea =bis(2-pyridylmethyl)amino-2-ethanoic acid) has been synthesized and characterized. It crystallizes in the monoclinic system P2(1)/c, a = 9.0057(11), b = 28.031(3), c = 8.5669(10) angstrom, beta = 104.267(2)degrees, V = 2095.9(4) angstrom(3), Z = 4. Crystal structure of 1 reveals a syn-anti carboxylate-bridged dinuclear complex, in which the coordination environment around each copper atom exhibits a distorted square-pyramid. Magnetic susceptibility measurement for 1 exhibits a weak intermolecular antiferromagnetic exchange interaction with 2J = -1.17(9) cm(-1). The cyclic voltammogram of 1 gives one oxidation and two reduction processes.
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收藏
页码：7 / 12
页数：6
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