Phase diagrams and rheological properties of cellulose ether solutions in magnetic field

被引:17
|
作者
Vshivkov, S. A. [1 ]
Rusinova, E. V. [1 ]
Galyas, A. G. [1 ]
机构
[1] Ural Fed Univ, Dept Chem, Ekaterinburg 620002, Russia
基金
俄罗斯基础研究基金会;
关键词
Phase diagram; Rheology; Magnetic field; Liquid crystal; Cellulose ethers; LIQUID-CRYSTALLINE SOLUTIONS; BENZYL-L-GLUTAMATE; NON-NEWTONIAN VISCOSITY; HYDROXYPROPYL CELLULOSE; CONCENTRATED-SOLUTIONS; AQUEOUS-SOLUTIONS; WATER SYSTEM; TRANSITIONS; POLYPEPTIDE; MACROMOLECULES;
D O I
10.1016/j.eurpolymj.2014.07.042
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The phase transitions and rheological properties of the hydroxyethyl cellulose-water, hydroxyethyl cellulose-DMAA, hydroxyethyl cellulose-DMF, hydroxypropyl cellulose-water, hydroxypropyl cellulose-DMF and ethyl cellulose-DMAA systems were studied. The regions of existence of the isotropic and anisotropic phases were determined. Application of a magnetic field is shown to be accompanied by a change in the relative viscosity by a factor of 1.3-4. The concentration dependences of viscosity in the presence of a magnetic field are described by curves with an extremum. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:326 / 332
页数:7
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