Nano-ceramic support materials for low temperature fuel cell catalysts

被引:93
|
作者
Lv, Haifeng [1 ]
Mu, Shichun [1 ]
机构
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China
基金
中国国家自然科学基金;
关键词
OXYGEN REDUCTION REACTION; NB-DOPED TIO2; TUNGSTEN CARBIDES/CARBON NANOTUBES; FORMIC-ACID ELECTROOXIDATION; MESOPOROUS TIN OXIDE; METHANOL OXIDATION; ELECTROCATALYTIC ACTIVITY; PLATINUM CATALYSTS; TITANIUM NITRIDE; HIGH-PERFORMANCE;
D O I
10.1039/c4nr00402g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Low temperature fuel cells (LTFCs) have received broad attention due to their low operating temperature, virtually zero emissions, high power density and efficiency. However, the limited stability of the catalysts is a critical limitation to the large scale commercialization of LTFCs. State of the art carbon supports undergo corrosion under harsh chemical and electrochemical oxidation conditions, which results in performance degradation of catalysts. Therefore, non-carbon materials which are highly oxidation resistant under strongly oxidizing conditions of LTFCs are ideal alternative supports. This minireview highlights the advances and scenarios in using nano-ceramics as supports to enhance the stability of catalysts, the solutions to improve electrical conductivity of nano-ceramic materials, and the synergistic effects between metal catalyst and support to help improve the catalytic activity and CO/SO2 tolerance of catalysts.
引用
收藏
页码:5063 / 5074
页数:12
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