Synthetic uses of thioesters of trifluoromethylated acids. Part 2. Reactions with alkenes

被引：34
|
作者：
Billard, T [1 ]
Roques, N [1 ]
Langlois, BR [1 ]
机构：
[1] Univ Lyon 1, Lab Synth Electrosynth & React Composes Organ Flu, CNRS, UMR 5622, F-69622 Villeurbanne, France
来源：
TETRAHEDRON LETTERS | 2000年 / 41卷 / 17期
关键词：
trifluoromethanethiosulfonates; trifluorothioacetates; photolysis; (trifluoromethyl)alkanes;
D O I：
10.1016/S0040-4039(00)00337-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The photolysis of trifluoromethanethiosulfonates (CF3SO2SR) or trifluorothioacetates (CF3COSR) in the presence of alkenes provides (trifluoromethyl)alkanes or beta-sulfanyl (trifluoromethyl)alkanes. The formation of these compounds can be controlled by the nature and the ratio of the reactants. (C) 2000 Published by Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：3069 / 3072
页数：4
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