Synthesis, structure and magnetic properties of binuclear 3d-metal complexes of new 3-(2-pyridyl)-6-phenyl-1,2,4-triazine derivative

被引：2

作者：

Nemytov, Alexey, I ^{[1
]}

Utepova, Irina A. ^{[1
,2
]}

Kiskin, Mikhail A. ^{[3
]}

Efimov, Nikolay N. ^{[3
]}

Fedin, Matvey, V ^{[4
,5
]}

Eremenko, Igor L. ^{[3
,6
]}

Musikhina, Alexandra A. ^{[1
,2
]}

Slepukhin, Pavel A. ^{[2
]}

Chupakhin, Oleg N. ^{[1
,2
]}

机构：

[1] Ural Fed Univ, 19 Mira Str, Ekaterinburg 620002, Russia

[2] Russian Acad Sci, I Ya Postovsky Inst Organ Synth, 22 S Kovalevskaya Str, Ekaterinburg 620108, Russia

[3] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, 31 Leninsky Prosp, Moscow 119991, Russia

[4] Russian Acad Sci, Int Tomog Ctr Inst, Siberian Branch, 3a Inst Skaya Str, Novosibirsk 630090, Russia

[5] Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia

[6] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Vavilova Str, Moscow 119334, Russia

来源：

POLYHEDRON | 2021年 / 193卷

基金：

俄罗斯基础研究基金会; 俄罗斯科学基金会;

关键词：

Binuclear complexes; 1,2,4-triazine; Magnetic properties; Nucleophilic substitution of hydrogen; ANTICANCER ACTIVITY; BSA-BINDING; TRIMETHYLACETATE COMPLEXES; LIGANDS; BEHAVIOR; CO(II); ZN(II); NI(II); CU(II); MCF-7;

D O I：

10.1016/j.poly.2020.114901

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel non-symmetric tridentate N,N,O-ligand was obtained by direct substitution of hydrogen in 3-(2-pyridyl)-6-phenyl-1,2,4-triazine. Three binuclear cobalt(II), copper(II) and zinc(II) carboxylate complexes of 3-(2-pyridyl)-5-(2-hydroxynaphthalen-1-yl)-6-phenyl-1,2,4-triazine anion (HL1), [M-2(Piv)(2)(L-1)(2)] (M = Co, Cu, Zn; Piv = Me3CCO2-), were synthesized and characterized by elemental analysis and IR spectroscopy. The complexes structures were determined by single crystal X-ray diffraction analysis. The magnetic property studies indicate that cobalt(II) complex exhibits weak ferromagnetic coupling (J = 1.2(1) cm(-1)) between two high-spin Co(II) ions linked by double mu-O phenoxo bridges. According to magnetic property studies as well as X- and Q-band EPR spectra for copper(II) complex, the specific structure of the Cu2O2 fragment leads to the predominance of dipole-dipole interactions and weak antiferromagnetic coupling (J = -3.64(3) cm(-1)). (C) 2020 Elsevier Ltd. All rights reserved.

引用

页数：8

共 50 条

[1] ELECTROCHEMICAL REDUCTION OF [3-(2-PYRIDYL)-5,6-DIPHENYL-1,2,4-TRIAZINE]
ELJAMMAL, A
GRAF, E
GROSS, M
ELECTROCHIMICA ACTA, 1986, 31 (11) : 1457 - 1465
[2] STRUCTURE OF 3,5-BIS(DIMETHYLAMINO)-6-PHENYL-1,2,4-TRIAZINE 1-IMIDE
LINDLEY, PF
BOYD, GV
NICOLAOU, GA
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 1487 - 1490
[3] ELECTROCHEMICAL REDUCTION OF IRON(II) COMPLEXES WITH [3-(2-PYRIDYL)-5,6-DIPHENYL-1,2,4-TRIAZINE]
ELJAMMAL, A
GRAF, E
GROSS, M
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 245 (1-2): : 201 - 221
[4] SPECTROPHOTOMETRIC DETERMINATION OF RUTHENIUM WITH 3-(2-PYRIDYL)-5,6-DIPHENYL-1,2,4-TRIAZINE
KAMRA, LC
AYRES, GH
ANALYTICA CHIMICA ACTA, 1975, 78 (02) : 423 - 429
[5] Synthesis, crystal structure and magnetic properties of new copper(II) complexes based on 3-(2-pyridyl)-1,2,4-triazole
Petrenko, Yuliia P.
Khomenko, Dmytro M.
Doroshchuk, Roman O.
Shova, Sergiu
Novitchi, Ghenadie
Piasta, Karolina
Gumienna-Kontecka, Elzbieta
Lampeka, Rostyslav D.
INORGANICA CHIMICA ACTA, 2020, 500
[6] SYNTHESIS AND MESOMORPHIC PROPERTIES OF FERROELECTRIC LIQUID-CRYSTALS BEARING 6-PHENYL-1,2,4-TRIAZINE RINGS
SUGITA, SI
TODA, S
YOSHIYASU, T
TERAJI, T
MURAYAMA, A
ISHIKAWA, M
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1993, 237 : 319 - 328
[7] 5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine
Eltayeb, Naser Eltaher
Teoh, Siang Guan
Ng, Shea-Lin
Fun, Hoong-Kun
Ibrahim, Kamarulazizi
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O1041 - O1042
[8] Influence of π stacking on the magnetic properties of the copper(II) complex with 6-phenyl-3-(2-pyridyl)-5-trifluoroacetylmethylidene-4,5-dihydro-1,2,4-triazine
A. M. Prokhorov
D. N. Kozhevnikov
V. L. Rusinov
O. N. Chupakhin
G. G. Aleksandrov
Yu. N. Shvachko
D. V. Starichenko
A. V. Korolev
D. V. Bukhvalov
V. V. Ustinov
Russian Chemical Bulletin, 2008, 57 : 561 - 566
[9] Influence of π stacking on the magnetic properties of the copper(II) complex with 6-phenyl-3-(2-pyridyl)-5-trifluoroacetylmethylidene-4,5-dihydro-1,2,4-triazine
Prokhorov, A. M.
Kozhevnikov, D. N.
Rusinov, V. L.
Chupakhin, O. N.
Aleksandrov, G. G.
Shvachko, Yu. N.
Starichenko, D. V.
Korolev, A. V.
Bukhvalov, D. V.
Ustinov, V. V.
RUSSIAN CHEMICAL BULLETIN, 2008, 57 (03) : 561 - 566
[10] Synthesis, structure, spectra and redox interconversions in copper(II) complexes of 5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine
Uma, R
Palaniandavar, M
Butcher, RJ
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (10): : 2061 - 2066

← 1 2 3 4 5 →