Aromatic Borataheterocycles: Surrogates for Cyclopentadienyl in Transition-Metal Complexes

被引：81
|
作者：
Ashe, Arthur J., III [1 ]
机构：
[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
来源：
ORGANOMETALLICS | 2009年 / 28卷 / 15期
关键词：
OLEFIN POLYMERIZATION CATALYSTS; LEWIS-ACID COMPLEX; B-N; COORDINATION CHEMISTRY; PI-COMPLEXES; TRICARBONYLCHROMIUM COMPLEXES; HETEROAROMATIC-COMPOUNDS; STABILIZED CARBANIONS; 5-MEMBERED RING; C-C;
D O I：
10.1021/om900308e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This review, describes the syntheses and coordination chemistry of selected unsaturated borataheterocycles, These compounds are formally derived from common heteroaromatic rings by the isoelectronic substitution of an anionic BH- group for a neutral CH group. Specifically included are the five-membered rings 1,2- and 1,3-thiaborolyls, derived from thiophene, 1,2-oxaborolyl. derived from furan, and 1,2-azaborolyl, derived from pyrrole. Also included is the six-membered ring 1,2-azaboratabenzene, derived from pyridine. These anionic rings can serve is surrogates for cyclopentadienyl in organometallic compounds.
引用
收藏
页码：4236 / 4248
页数：13
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