Synthesis of Copolymers Containing Double Spiro Orthocarbonate and Used as Anti-shrinkage Additives in Epoxy Resin Composite

被引：11

作者：

Xu, Xiaoqiang ^{[1
,3
]}

Zhou, Lin ^{[2
]}

Liang, Bing ^{[2
]}

Wu, Yumin ^{[1
]}

Wang, Changsong ^{[2
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Chem Engn, Qingdao, Peoples R China

[2] Shenyang Univ Chem Technol, Coll Mat Sci & Engn, Shenyang 110142, Peoples R China

[3] Panjin Vocat & Tech Coll, Panjin, Peoples R China

来源：

POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING | 2014年 / 53卷 / 08期

基金：

中国国家自然科学基金;

关键词：

Epoxy resin; Mechanical property; Prepolymer; Spiro orthocarbonate; Volume shrinkage; FLAME-RETARDANT; CATIONIC PHOTOPOLYMERIZATION; VOLUME CHANGE; POLYMERIZATION;

D O I：

10.1080/03602559.2013.869697

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel copolymer containing a double spiro orthocarbonate structure, poly 3-methylene-9-methyleneoxy-3,9-Bis(hydroxymethyl)-1,5,7,11- tetraoxaspiro[5.5] undecane (SOC), was synthesized. The structure of SOC was confirmed by H-1, C-13 NMR and FTIR spectra. Prepolymer (SOCP) reacting from SOC and 2,4-toluene dii-socynate (TDI) was prepared and used as anti-shrinkage additives in the cationic polymerization of epoxy resin (EP-51). The volume changes of the cured epoxy resin containing SOCP were investigated by density measurements with an electronic hydrometer. The mechanical properties of the modified epoxy resin were investigated by adhesive strength, impact strength and flexural strength, while thermal properties were investigated by thermal gravimetric analysis (TGA).

引用

页码：753 / 759

页数：7

共 19 条

[1] Study on epoxy resin modified with prepolymer containing spiro orthocarbonate
Wang, CS
Zhou, BL
ACTA POLYMERICA SINICA, 1998, (02) : 214 - 218
[2] Study on epoxy resin modified with prepolymers containing spiro orthocarbonate
Wang, CS
Zhou, BL
JOURNAL OF MATERIALS SCIENCE LETTERS, 1999, 18 (15) : 1259 - 1262
[3] Novel diol Spiro orthocarbonates derived from glycerol as anti-shrinkage additives for the cationic photopolymerization of epoxy monomers
Acosta Ortiz, Ricardo
Berlanga Duarte, Maria Lydia
Savage Gomez, Amy Grace
Sangermano, Marco
Garcia Valdez, Aida E.
POLYMER INTERNATIONAL, 2010, 59 (05) : 680 - 685
[4] Dental restorative composite resins containing asymmetric spiro orthocarbonate for the reduction of volumetric shrinkage
Hwang, M
Kim, CK
POLYMER-KOREA, 2004, 28 (04) : 321 - 327
[5] STUDY ON CURING REACTION OF EPOXY-RESIN MODIFIED WITH PREPOLYMERS CONTAINING SPIRO ORTHOCARBONATE
PAN, CY
QI, LW
BAI, RK
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1995, 33 (13) : 2151 - 2155
[6] Shrinkage properties of a modified dental resin composites containing a novel spiro-orthocarbonate expanding monomer
Sun, Xiang
Li, Yuncong
Xiong, Jie
Hu, Xiaoyi
Chen, Jihua
MATERIALS LETTERS, 2011, 65 (23-24) : 3586 - 3589
[7] Election of Anti-shrinkage Curing Microcapsule Core Material in Self-healing Epoxy Resin
Zhang, Yanfang
Wang, Youyuan
Zheng, Rongliang
Zhongguo Dianji Gongcheng Xuebao/Proceedings of the Chinese Society of Electrical Engineering, 2022, 42 (04): : 1252 - 1259
[8] Synthesis of copolymers containing a spiro orthocarbonate moiety and evaluation of the volume change during their cationic crosslinking
Kume, Makoto
Maki, Yuya
Ochiai, Bungo
Endo, Takeshi
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (24) : 7040 - 7053
[9] Synthesis of an epoxy functionalized spiroorthocarbonate used as low shrinkage additive in cationic UV curing of an epoxy resin
Politecnico di Torino, Dipartimento di Scienza dei Materiali e Ingegneria Chimica, Cso Duca Degli Abruzzi 24, 10129 Torino, Italy
不详
European Polymer Journal, 2008, 44 (04): : 1046 - 1052
[10] Synthesis of an epoxy functionalized spiroorthocarbonate used as low shrinkage additive in cationic UV curing of an epoxy resin
Sangermano, Marco
Acosta Ortiz, Ricardo
Puente Urbina, Bertha A.
Berlanga Duarte, Lydia
Garcia Valdez, Aida E.
Guerrero Santos, Ramiro
EUROPEAN POLYMER JOURNAL, 2008, 44 (04) : 1046 - 1052

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