Semi-empirical calculation of the transport properties of the CH4-noble gas mixtures from the interaction potential energy function using the inversion method

被引:0
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作者
Haghighi, B [1 ]
Fathabadi, M
Papari, MM
机构
[1] Univ Birjand, Dept Chem, T&TPRL, Birjand 97175615, Southern Khoras, Iran
[2] Shiraz Univ, Shiraz, Far Province, Iran
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Viscosity, diffusion coefficients, and thermal diffusion factors for five equimolar binary gas mixtures of CH4-noble gases have been determined from the principle of corresponding states of viscosity by the inversion technique. The Lennard-Jones 12-6 potential energy function is used as the initial model potential required by the technique. The interaction potential energies from the inversion procedure reproduce viscosities within 1%, diffusion coefficients within 5%, and thermal diffusion factors within 25%.
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页码:1824 / 1831
页数:8
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