μ-trithiocyanurato-κ4N1,S2: N3,S4-bis[(N,N,N′,N",N"-pentamethyldiethylenetriamine-κ3,N,N′,N")zinc(II)] perchlorate monohydrate

被引：2
|
作者：
Travnicek, Zdenek
Marek, Jaromir
Cermakova, Sarka
机构：
[1] Palacky Univ, Fac Sci, Dept Inorgan Chem, CZ-77147 Olomouc, Czech Republic
[2] Masaryk Univ, Fac Sci, Inst Expt Biol, Lab Funct Genom & Prote, CZ-62500 Brno, Czech Republic
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807007349
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Zn-2(C3N3S3)(C9H23N3)(2)]ClO4 (.) H2O, the dinuclear Zn-II metal centres are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a distorted trigonal bipyramidal geometry and bonded to three diethylenetriamine N atoms, and an S and an N atom of ttc. The crystal structure is stabilized by O-H (.) (.) (.) O, O-H (.) (.) (.) S, C H (.) (.) (.) S and C-H (.) (.) (.) O interactions connecting the cations, the ClO4- anions and the water molecules.
引用
收藏
页码：m795 / m797
页数：3
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