Preparation of allyl sulfoxides by palladium-catalyzed allylic alkylation of sulfenate anions

被引：47
|
作者：
Maitro, Guillaume [1 ]
Prestat, Guillaume [1 ]
Madec, David [1 ]
Poli, Giovanni [1 ]
机构：
[1] Univ Paris 06, Inst Chim Mol, Chim Organ Lab, CNRS,UMR 7611,FR 2769, F-75252 Paris 05, France
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 19期
关键词：
D O I：
10.1021/jo061359u
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium-catalyzed allylic alkylation of sulfenate anions, generated from beta-sulfinylesters by retro-Michael reaction, can take place under biphasic conditions. This new reaction provides a simple, mild, and efficient route to allyl sulfoxides in good yields.
引用
收藏
页码：7449 / 7454
页数：6
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