Low-Cost and Sustainable Organic Thermoelectrics Based on Low-Dimensional Molecular Metals

被引:49
|
作者
Huewe, Florian [1 ,2 ]
Steeger, Alexander [1 ,2 ]
Kostova, Kalina [3 ]
Burroughs, Laurence [4 ]
Bauer, Irene [5 ]
Strohriegl, Peter [6 ]
Dimitrov, Vladimir [3 ]
Woodward, Simon [4 ]
Pflaum, Jens [1 ,2 ]
机构
[1] Julius Maximilian Univ Wurzburg, Expt Phys 6, D-97074 Wurzburg, Germany
[2] Bavarian Ctr Appl Energy Res ZAE Bayern eV, D-97074 Wurzburg, Germany
[3] Bulgarian Acad Sci, Inst Organ Chem, Ctr Phytochem, Sofia 1113, Bulgaria
[4] Univ Nottingham, GSK Carbon Neutral Lab Sustainable Chem, Jubilee Campus, Nottingham NG7 2GG, England
[5] Univ Bayreuth, Expt Phys 2, D-95440 Bayreuth, Germany
[6] Univ Bayreuth, Macromol Chem 1, D-95440 Bayreuth, Germany
关键词
POWER; CONDUCTIVITY; CONDUCTORS; DEVICES; FIGURE; HEAT;
D O I
10.1002/adma.201605682
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Thermoelectric generator composed of crystalline radical ion salts: The unipolar charge transport along the molecular stacks facilitates complementary p-and n-type organic thermoelectric materials of high electrical conductivity and of 1D electronic structure. The specific power output of 5 mW cm(-2) and the zT > 0.15 below 40 K demonstrate a new field of low-temperature thermoelectric applications unlocked by organic metals.
引用
收藏
页数:7
相关论文
共 50 条
  • [1] Low-dimensional thermoelectrics
    Balandin, A
    PHYSICS OF LOW-DIMENSIONAL STRUCTURES, 2000, 5-6 : U1 - U1
  • [2] Low-dimensional thermoelectrics.
    Dresselhaus, MS
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U1240 - U1240
  • [3] Investigation of low-dimensional thermoelectrics
    Dresselhaus, M. S.
    Lin, Y. M.
    Cronin, S. B.
    Black, M. R.
    Rabin, O.
    Dresselhaus, G.
    THERMAL CONDUCTIVITY 26: THERMAL EXPANSION 14, 2005, 26 : 3 - 15
  • [4] Cyclotron resonance in low-dimensional molecular metals
    Hill, S
    SYNTHETIC METALS, 1999, 103 (1-3) : 1809 - 1809
  • [5] Seebeck coefficient in correlated low-dimensional organic metals
    Shahbazi, M.
    Bourbonnais, C.
    PHYSICAL REVIEW B, 2016, 94 (19)
  • [6] Fermi surfaces of low-dimensional organic metals and superconductors - Conclusion
    不详
    FERMI SURFACES OF LOW-DIMENSIONAL ORGANIC METALS AND SUPERCONDUCTORS, 1996, 134 : 143 - 145
  • [7] ORTHOGONALITY EXPONENTS IN LOW-DIMENSIONAL METALS
    SCHONHAMMER, K
    PROGRESS OF THEORETICAL PHYSICS SUPPLEMENT, 1991, (106): : 147 - 156
  • [9] INSITU INVESTIGATIONS OF THE CONDUCTION MECHANISMS IN LOW-DIMENSIONAL ORGANIC SEMICONDUCTORS AND METALS
    SCHMEISSER, D
    GOPEL, W
    BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1993, 97 (03): : 372 - 378
  • [10] Molecular design for low-cost organic photovoltaic materials
    Yang, Ni
    Zhang, Shaoqing
    Cui, Yong
    Wang, Jianqiu
    Cheng, Shuohan
    Hou, Jianhui
    NATURE REVIEWS MATERIALS, 2025,