Metal-ligand interactions in bis(isodicyclopentadienyl)iron complexes

被引：6
|
作者：
Herber, RH [1 ]
Gattinger, I
Köhler, FH
机构：
[1] Hebrew Univ Jerusalem, Racah Inst Phys, IL-19104 Jerusalem, Israel
[2] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany
来源：
INORGANIC CHEMISTRY | 2000年 / 39卷 / 04期
关键词：
D O I：
10.1021/ic991258x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Fe-57 Mossbauer spectra of bis(isocyclopentadienyl)iron and its cationic form have been determined over the temperature range 90 less than or equal to T less than or equal to 300 K, and the hyperfine interaction and lattice dynamical parameters extracted from these data are compared to a number of structurally related oganometallics. The metal d-orbital involvement in the bonding to the cyclic ligands is discussed in detail.
引用
收藏
页码：851 / +
页数：4
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