Synthesis and absolute configuration of a new chiral [2.2]paracyclophane-based diene

被引：0
|
作者：
Minuti, L
Taticchi, A
Rosini, C
Lanari, D
Marrocchi, A
Superchi, S
机构：
[1] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy
[2] Univ Basilicata, Dipartimento Chim, I-85100 Potenza, Italy
来源：
TETRAHEDRON-ASYMMETRY | 2002年 / 13卷 / 12期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of a new enantiomerically pure diene, (S)-(+)-1 is reported. The absolute configuration of 1 was determined by non-empirical analysis of its CD spectrum. The synthesis and resolution of the racemic beta-diketone 4 into its constituent enantiomers by the SAMP-hydrazone method is described. The enantiopure beta-diketone (S)-(+)-4 was then converted to diene (S)-(+)-1 by a two-stage reaction sequence. Structural analysis of the products by H-1 and C-13 NMR spectroscopy is also presented. (C) 2002 Elsevier Science Ltd. All rights reserved.
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页码：1257 / 1263
页数：7
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