Crystal structure of [Rh(H2O)5Cl](C7H7O3S)2 and Cs[Rh(H2O)5NO3](C7H7O3S)3•H2O

被引：5

作者：

Vorobieva, S. N. ^{[1
,2
]}

Baidina, I. A. ^{[1
]}

Belyaev, A. V. ^{[1
]}

Korolkov, I. V. ^{[1
,2
]}

Alferova, N. I. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia

[2] Novosibirsk Natl Res State Univ, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 56卷 / 08期

关键词：

rhodium; acido-penta-aqua complexes; coordination compounds; crystal structure; RH-103; NMR; COMPLEXES;

D O I：

10.1134/S0022476615080235

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structures of the compounds with the composition [Rh(H2O)(5)Cl](C7H7O3S)(2) (I) and Cs[Rh(H2O)(5)NO3](C7H7O3S)(3)aEuro cent H2O (II) are determined. Crystallographic data for I: a = 10.063(10) , b = 7.771(8) , c = 13.524(15) ; beta = 100.44(3)A degrees, space group P2(1), Z = 2, d (calc) = 1.823 g/cm(3); for II: a = 16.221(3) , b = 9.646(19) , c = 21.307(4) , beta = 92.06(3)A degrees, space group P2(1), Z = 8, d (calc) = 1.833 g/cm(3). The compounds are characterized by IR spectroscopy and powder X-ray diffraction. The rhodium atoms have a distorted octahedral environment consisting of five oxygen atoms of coordinated water molecules and one chloride ion (I)/oxygen atom of the nitrate ion (II) with the following distances: Rh-OH2O of 1.993-2.075 and Rh-Cl of 2.270 for I; Rh- of 1.996-2.031 and Rh- of 1.990 for II.

引用

页码：1606 / 1612

页数：7

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