Highly efficient heterogeneous procedure for the conjugate addition of amines to electron deficient alkenes

被引：6
|
作者：
Liang XueZheng [1 ]
Quan NanNan [1 ]
Wang Jian [1 ]
Yang JianGuo [1 ,2 ]
机构：
[1] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
[2] Penn State Univ, Dept Mat Sci & Engn, Energy Inst, University Pk, PA 16802 USA
来源：
SCIENCE IN CHINA SERIES B-CHEMISTRY | 2009年 / 52卷 / 07期
关键词：
heterogeneity; conjugate addition; chemoselectivity; catalysis; solvent-free; ASYMMETRIC MICHAEL ADDITION; IONIC LIQUID; ORGANOCATALYSTS; NITROOLEFINS; MALONONITRILE; NITROALKENES; PYRROLIDINE; ALDEHYDES; KETONES; SYSTEM;
D O I：
10.1007/s11426-009-0075-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The novel efficient procedure has been developed for the conjugate addition of amines to electron deficient alkenes. K2CO3 supported on different carriers have been synthesized for the conjugate addition of amines and alkenes. After optimizing the reaction conditions, K2CO3/MgO was chosen as the most efficient catalyst for the reactions. The results showed that the catalyst was very efficient for the conjugate addition of amines to electron deficient alkenes with the excellent yields in several minutes. Operational simplicity, without need of any solvent, low cost of the catalyst used, high yields, reusability, excellent chemoselectivity, and applicability to large-scale reactions are the key features of this methodology.
引用
收藏
页码：874 / 878
页数：5
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