RETRACTED: A Core-Substituted Naphthalene Diimide Fluoride Sensor (Retracted Article)

被引：192

作者：

Bhosale, Sheshanath V. ^{[1
]}

Bhosale, Sidhanath V. ^{[2
]}

Kalyankar, Mohan B. ^{[1
,2
]}

Langford, Steven J. ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[2] N Maharashtra Univ, Dept Organ Chem, Jalgaon 425001, India

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 23期

基金：

澳大利亚研究理事会;

关键词：

COLORIMETRIC ANION SENSORS; THIOUREA BINDING-SITES; OLIGOINDOLE FOLDAMERS; PROTON-TRANSFER; LIPID-BILAYERS; RECEPTORS; UREA; RECOGNITION; HYDROGEN; WATER;

D O I：

10.1021/ol9022722

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and characterization of a highly fluorescent core-substituted naphthalene diimide sensor (phi = 0.34) bearing a bis-sulfonamide group is described. The compound shows a unique selectivity and reactivity for the fluoride ion over other anions in CHCl3 by a two-stage deprotonation process leading to a colorimetric response. In DMSO solution, the sensor is shown to be highly selective for fluoride (K-a similar to 10(6) M-1) over other anions with more pronounced changes In absorption characteristics.

引用

页码：5418 / 5421

页数：4

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