Investigation of polyethylene helical conformations:: Theoretical study by vibrational Raman optical activity

被引：14

作者：

Liegeois, Vincent ^{[1
]}

Quinet, Olivier ^{[1
]}

Champagne, Benoit ^{[1
]}

机构：

[1] Fac Univ Notre Dame Paix, Lab Chim Theor Appl, B-5000 Namur, Belgium

来源：

INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY | 2006年 / 106卷 / 15期

关键词：

vibrational Raman optical activity; polyethylene; helicity; theoretical simulations;

D O I：

10.1002/qua.21054

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using theoretical simulations on polyethylene segments, it is demonstrated that vibrational Raman optical activity is highly sensitive to helicity, more than the conventional Raman technique. Therefore, it can be used to probe helicity and conformations of synthetic polymers. (c) 2006 Wiley Periodicals, Inc.

引用

页码：3097 / 3107

页数：11

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