Preparation of PO43-, P2O74- anion-pillared nanocrystalline Mg-Al and Zn-Al layered double hydroxides in microwave fields

被引:0
|
作者
Zhang, ZJ
Mei, XJ
Fen, LR
Lu, SR
Qiu, FL [1 ]
机构
[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
[2] Sichuan Fire Res Inst Publ Safety Minist, Chengdu 611830, Peoples R China
关键词
nanocrystalline; the anion-exchange method; microwave; layered double hydroxides;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Using nanocrystalline [Mg-Al-CO3] and [Zn-Al-CO3] as precursors, [Mg-Al-PO4], [Zn-Al-PO4], [Mg-Al-P2O7] and [Zn-Al-P2O7] have been successfully synthesized by a direct reaction with the free PO43- or P2O74- using the microwave techniques and the anion-exchange method. And the samples thus obtained were characterized by TEM, FT-IR and XRD. The results show that the initial interlayer carbonate ions can be completely replaced by the free PO43- or P2O74- under controlled microwave conditions employed for a short time.
引用
收藏
页码:867 / 870
页数:4
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