FeCl3-NaI mediated reactions of aryl azides with 3,4-dihydro-2H-pyran:: a convenient synthesis of pyranoquinolines

被引：37
|
作者：
Kamal, A [1 ]
Prasad, BR [1 ]
Ramana, AV [1 ]
Babu, AH [1 ]
Reddy, KS [1 ]
机构：
[1] Indian Inst Chem Technol, Div Organ Chem, Hyderabad 500007, Andhra Pradesh, India
来源：
TETRAHEDRON LETTERS | 2004年 / 45卷 / 17期
关键词：
aryl azide; pyranoquinolines; ferric chloride; sodium iodide; reductive cyclization;
D O I：
10.1016/j.tetlet.2004.02.146
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The tetrahydroquinoline moiety is an important structural component of a number of natural products. The reaction of aryl azides with 3,4-dihydro-2H-pyran in the presence of FeCl3-NaI affords the corresponding tetrahydroquinoline derivatives in an efficient manner. Most of the cyclizations exhibited cis selectivity. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3507 / 3509
页数：3
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