Enantioselective epoxidation of olefins catalyzed by Mn (salen)/MCM-41 synthesized with a new anchoring method

被引：157
|
作者：
Xiang, S [1 ]
Zhang, YL [1 ]
Xin, Q [1 ]
Li, C [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2002年 / 22期
关键词：
D O I：
10.1039/b206104j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New immobilization of the chiral Mn(salen) complex through the complexation of manganese by oxygen atoms of the phenoxyl groups grafted on the surface of MCM-41 leads to a markedly higher ee than for the free complex.
引用
收藏
页码：2696 / 2697
页数：2
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