Selective remote C-H sulfonylation of aminoquinolines with arylsulfonyl chlorides via copper catalysis

被引：141

作者：

Liang, Hong-Wen ^{[1
]}

Jiang, Kun ^{[1
]}

Ding, Wei ^{[1
]}

Yuan, Yi ^{[1
]}

Shuai, Li ^{[1
]}

Chen, Ying-Chun ^{[1
]}

Wei, Ye ^{[1
]}

机构：

[1] Third Mil Med Univ, Coll Pharm, Chongqing 400038, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 95期

关键词：

UNSYMMETRICAL DIARYL SULFONES; BOND FUNCTIONALIZATION; DIRECT ARYLATION; N-OXIDES; PALLADIUM; ARYL; ALKYLATION; C(SP(3))-H; ACIDS; C(SP(2))-H;

D O I：

10.1039/c5cc05527j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper-catalysed direct C-H bond sulfonylation of aminoquinolines using commercially available and inexpensive arylsulfonyl chlorides as the sulfonylation reagents is described. The reactions took place exclusively at the C5-H position of the quinoline rings and tolerated a wide spectrum of functional groups. Moreover, synthetic transformations of the sulfonylated products led to useful compounds.

引用

页码：16928 / 16931

页数：4

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