Ligand-free Pd/Cu-catalyzed decarboxylative coupling of aryl iodides with α-oxocarboxylates

被引：9

作者：

Ji, Yongfeng ^{[1
]}

Yang, Xiaomin ^{[1
]}

Mao, Weixi ^{[1
]}

机构：

[1] Hebei North Univ, Dept Chem, Coll Sci, Zhangjiakou 075000, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2014年 / 28卷 / 09期

关键词：

Pd/Cu-catalyzed; alpha-oxocarboxylates; decarboxylative coupling; aryl iodide; KETONES; HYPERICIN; HALIDES; ACIDS;

D O I：

10.1002/aoc.3181

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This paper describes a palladium/copper-catalyzed decarboxylative coupling of aryl iodides with alpha-oxocarboxylates. The cross-coupling reaction gives high chemical yields of aryl ketones and has wide functional group tolerance, making the transformation an attractive alternative to the traditional cross-coupling approaches for aryl ketones. Copyright (C) 2014 John Wiley & Sons, Ltd.

引用

页码：678 / 680

页数：3

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