Preparation and organic transformation reactions of CpFe(CO)2SCO-3-C6H4-SO2Cl

被引：7

作者：

El-khateeb, M ^{[1
]}

Younes, A ^{[1
]}

机构：

[1] Jordan Univ Sci & Technol, Fac Sci, Dept Chem, Irbid 22110, Jordan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 664卷 / 1-2期

关键词：

iron; thiocarboxylate; nucleophilic substitution; structures; sulfonates;

D O I：

10.1016/S0022-328X(02)02015-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the iron sulfides (mu-S-x)[CpFe(CO)(2)](2) with 3-ClCOC6H4SO2Cl gave the novel organoiron thiocarboxylate complex CpFe(CO)(2)SCO-3-C6H4SO2Cl which contains a free sulfonyl chloride group. This complex reacts with nucleophiles such as R2NH, ArOH and RSH to give stable complexes CpFe(CO)(2)SCO-3-C6H4SO2NR2, CpFe(CO)(2)SCO-3-C6H4SO2OAr, and CpFe(CO)(2)SCO-3-C6H4SO2SR, respectively. The crystal structure of CpFe(CO)(2)SCO-3-C6H4SO2N(CH3)CH2Ph has been determined: space group: P2(1)/c, a = 17.9594(5), b = 9.2395(2), c = 13.4341(4) Angstrom,beta = 95.403(2)degrees, V = 2219.26(10) Angstrom(3) and Z = 4. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：228 / 233

页数：6

共 50 条

[1] SYNTHESIS AND CLEAVAGE REACTIONS OF THIOCARBONYL-BRIDGED CP2FE2(CO)3CS, AND PREPARATION OF CARBENE COMPLEXES CPFE(CO)C(N2C2H6)SNPH3 AND ]CPFE(CO)2C(OME)2]PF6
QUICK, MH
ANGELICI, RJ
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 160 (01) : 231 - 239
[2] Condensation reactions of trifluoronitrosomethane CF3NO with sulfanilamide H2NC6H4SO2NH2 - Preparation of CF3NNC6H4SO2NH2, CF3NNC6H4SO2NNCF3, CH3C(O)N(H)C6H4SO2NNCF3 and CF3C(O)N(H)C6H4SO2NH2
Minkwitz, R
Jakob, J
Winter, A
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1997, 52 (05): : 647 - 654
[3] Condensation Reactions of Trifluoronitrosomethane CF3NO with Sulfanilamide H2NC6H4SO2NH2 - Preparation of CF3NNC6H4SO2NH2, CF3NNC6H4SO2NNCF3, CH3C(O)N(H)C6H4SO2NNCF3 and CF3C(O)N(H)C6H4SO2NH2
Minkwitz, R.
Jakob, J.
Winter, A.
Zeitschrift fuer Naturforschung. B, Journal of Chemical Sciences, 52 (05):
[4] Condensation reactions of trifluoronitrosomethane CF3NO with sulfanilamide H2NC6H4SO2NH2 - Preparation of CF3NNC6H4SO2NH2, CF3NNC6H4SO2NNCF3, CH3C(O)N(H)C6H4SO2NNCF3
Minkwitz, Rolf
Jakob, Jens
Winter, Andreas
1997, Verlag der Zeitschrift fur Naturforschung (52):
[5] Multifunctional iron thiocarboxylate complexes: synthesis, reactivity and structure of CpFe(CO)2SCO-3,5-C6H4(COCl)2
El-khateeb, Mohammad
Asali, Khalil J.
Jibril, Ibrahim
Abuseni, Anas
Goerls, Helmar
Weigand, Wolfgang
TRANSITION METAL CHEMISTRY, 2009, 34 (04) : 419 - 424
[6] The first selenosulfonate complexes CpFe(CO)2SeSO2R:: preparation and structure of CpFe(CO)2SeSO2C6H5
El-Khateeb, M
Obidate, T
POLYHEDRON, 2001, 20 (18) : 2393 - 2396
[7] Multifunctional iron thiocarboxylate complexes: synthesis, reactivity and structure of CpFe(CO)2SCO-3,5-C6H4(COCl)2
Mohammad El-khateeb
Khalil J. Asali
Ibrahim Jibril
Anas Abuseni
Helmar Görls
Wolfgang Weigand
Transition Metal Chemistry, 2009, 34 : 419 - 424
[8] 3 POLYCHLOROMONONITROBENZENES - C6H3CL2NO2, C6H2CL3NO2 AND C6HCL4NO2
BHAR, A
AUNE, JP
BENALICHERIF, N
BENMENNI, L
GIORGI, M
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 256 - 260
[9] Iron dithiocarbonate complexes:: Structure of CpFe(CO)2SC(S)O-4-C6H4Cl
El-Khateeb, Mohammad
Asali, Khalil J.
Lataifeh, Anas
POLYHEDRON, 2006, 25 (07) : 1695 - 1699
[10] The preparation and characterisation of [Co(py)4C7H4SO3NC1]Cl.H2O
Deng, RMK
Sethatho, DT
BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, 1997, 11 (02) : 155 - 158

← 1 2 3 4 5 →