Cu(OAc)2-2,4-Lutidine-ZnCl2 as an Effective Catalyst of Functionalization of Isobutylene Oligomers and 1,2-Polybutadiene with Methyl Diazoacetate

被引：1
|
作者：
Gareev, V. F. [1 ]
Yangirov, T. A.
Volodina, V. P.
Sultanova, R. M.
Biglova, R. Z.
Dokichev, V. A.
机构：
[1] Russian Acad Sci, Inst Organ Chem, Ufa Sci Ctr, Ufa 450001, Bashkortostan, Russia
来源：
RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2009年 / 82卷 / 07期
关键词：
CYCLOPROPANATION;
D O I：
10.1134/S1070427209070271
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The possibility of [1+2]-cycloaddition of methoxycarbonylcarbene generated by catalytic decomposition of methyl diazoacetate in the presence of the Cu(OAc)(2)-2,4-lutidine-ZnCl2 system to the carbon-carbon double bound in isobutylene oligomers and syndiotactic 1,2-polybutadiene was examined. A comparative analysis of physicochemical properties of the starting compounds and their functionalized products was performed.
引用
收藏
页码：1305 / 1309
页数：5
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