The role of neighbouring group participation in TTF-mediated 'radical-polar crossover' reactions:: trapping of aliphatic radicals by TTF+•

被引：25

作者：

Bashir, N ^{[1
]}

Murphy, JA ^{[1
]}

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 07期

关键词：

D O I：

10.1039/b000786m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Trapping of secondary alkyl radicals with tetrathiafulvalenium tetrafluoroborate (TTF+.BF4-) leads to S-alkyltetrathiafulvalenium tetrafluoroborate salts; the solvolysis of such salts is critically dependent on the presence of appropriately sited neighbouring groups.

引用

页码：627 / 628

页数：2

共 6 条

[1] On the mechanism of the tetrathiafulvalene-mediated radical-polar crossover reactions
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Callaghan, O
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TETRAHEDRON LETTERS, 1997, 38 (35) : 6255 - 6258
[2] Stereocontrolled synthesis of complex polycycles using tetrathiafulvalene mediated radical-polar crossover reactions
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[4] Application of the stabilization effect of a silyl group in radical-polar crossover reactions enabled by photoredox-neutral catalysis
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[5] Access to functionalized alkynylcyclopropanes via reductive radical-polar crossover-based reactions of 1,3-enynes with alkyl radicals
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[6] The Cp2TiPh-mediated reductive radical cyclization of cyanoketones and related reactions.: Efficient trapping of ketyl radicals by Cp2TiPh-coordinated polar multiple bonds
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JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (09): : 3224 - 3229

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