Jahn-Teller distortion in C60- ion studied by solid state 13C NMR spectroscopy

被引：3

作者：

Shao, QF ^{[1
]}

Chen, J

Wu, TL

Cai, RF

Huang, ZE

机构：

[1] Fudan Univ, Res Ctr Measurement, Shanghai 200433, Peoples R China

[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

来源：

ACTA PHYSICA SINICA | 2000年 / 49卷 / 03期

关键词：

D O I：

10.7498/aps.49.557

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Jahn-Teller distortion in C-60(-) ion has been studied by C-13 nuclear magnetic resonance spectroscopy in the solid samples KC60(THF) and KC60(THF)(x)(0 < x < 1). Solvating K+ ion by THF can change electronic states of C-60(-) ion. When C-60(-) is less affected by K+ ion, the ground state is a (2)A state, which is in good agreement with the ab initio calculation for the free C-60(-) ion. When C-60(-) is perturbed strongly by K+ ion, however, the ordering is inverted, leading to the more stable E-2 state.

引用

页码：557 / 559

页数：3