Electrochemical hydrogenation of nanocrystalline face-centered cubic Co powder

被引：29
|
作者：
Chung, S. -R. [1 ]
Wang, K. -W. [2 ]
Teng, M. -H. [3 ]
Perng, T. -P. [1 ,4 ,5 ]
机构：
[1] Natl Tsing Hua Univ, Dept Mat Sci & Engn, Hsinchu 300, Taiwan
[2] Natl Cent Univ, Inst Mat Sci & Engn, Chungli 320, Taiwan
[3] Natl Taiwan Univ, Dept Geosci, Taipei 106, Taiwan
[4] Yuan Univ, Dept Chem Engn & Mat Sci & Engn, Chungli 320, Taiwan
[5] Yuan Univ, Fuel Cell Res Ctr, Chungli 320, Taiwan
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2009年 / 34卷 / 03期
关键词：
Electrochemical hydrogenation; Co; Discharge capacity; FCC; HCP; METAL HYDRIDE ELECTRODES; STORAGE ALLOYS; CRYSTALLINE CO; PARTICLES; REDUCTION; BEHAVIORS; BATTERIES; LITHIUM; SI;
D O I：
10.1016/j.ijhydene.2008.11.073
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Nanocrystalline face-centered cubic (FCC) Co powder encapsulated within graphite layers was fabricated by an arc discharge method. Its electrochemical hydrogenation properties were investigated and compared with those of the hexagonal close packed (HCP) structure. Both exhibited a similar stabilized discharge capacity of approximately 350 mAh/g that can be attributed to the CoHx/Co reaction. During the cyclic charge/discharge, transition between HCP-Co and FCC-Co took place. Graphite encapsulation was beneficial to the cycle stability of the FCC powder. (C) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：1383 / 1388
页数：6
相关论文
共 50 条
  • [1] New twinning route in face-centered cubic nanocrystalline metals
    Lihua Wang
    Pengfei Guan
    Jiao Teng
    Pan Liu
    Dengke Chen
    Weiyu Xie
    Deli Kong
    Shengbai Zhang
    Ting Zhu
    Ze Zhang
    Evan Ma
    Mingwei Chen
    Xiaodong Han
    Nature Communications, 8
  • [2] New twinning route in face-centered cubic nanocrystalline metals
    Wang, Lihua
    Guan, Pengfei
    Teng, Jiao
    Liu, Pan
    Chen, Dengke
    Xie, Weiyu
    Kong, Deli
    Zhang, Shengbai
    Zhu, Ting
    Zhang, Ze
    Ma, Evan
    Chen, Mingwei
    Han, Xiaodong
    NATURE COMMUNICATIONS, 2017, 8
  • [3] Magnetic properties of face-centered cubic Co films
    Chen, YT
    Jen, SU
    Yao, YD
    Wu, JM
    Lee, CC
    Sun, AC
    IEEE TRANSACTIONS ON MAGNETICS, 2006, 42 (02) : 278 - 282
  • [4] In situ observation of deformation processes in nanocrystalline face-centered cubic metals
    Kobler, Aaron
    Brandl, Christian
    Hahn, Horst
    Kuebel, Christian
    BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 2016, 7 : 572 - 580
  • [5] THERMODYNAMICS OF FACE-CENTERED TETRAGONAL FACE-CENTERED CUBIC TRANSITIONS IN INDIUM ALLOYS
    POLOVOV, VM
    PONYATOV.EG
    ZHURNAL EKSPERIMENTALNOI I TEORETICHESKOI FIZIKI, 1973, 64 (03): : 937 - 945
  • [6] STATISTICS OF A FACE-CENTERED CUBIC FERROMAGNET
    DEMPSEY, E
    TERHAAR, D
    PHYSICAL REVIEW, 1954, 95 (02): : 651 - 652
  • [7] On the properties of face-centered cubic fullerites
    Magomedov, MN
    PHYSICS OF THE SOLID STATE, 2005, 47 (04) : 785 - 794
  • [8] VISCOPLASTICITY OF FACE-CENTERED CUBIC METALS
    LEROY, M
    OFFRET, S
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1972, 273 (01): : 29 - &
  • [9] On the properties of face-centered cubic fullerites
    M. N. Magomedov
    Physics of the Solid State, 2005, 47 : 785 - 794
  • [10] Twinning propensity in nanocrystalline face-centered cubic, body-centered cubic, and hexagonal close-packed metals
    Boyko, V. S.
    Kezerashvili, R. Ya.
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2014, 75 (10) : 1119 - 1123
12345