SIMPLE GRINDING-INDUCED REACTIONS OF 2-AMINOBENZYL ALCOHOL AND BENZALDEHYDE DERIVATIVES, A RAPID SYNTHETIC ROUTE TO 3,1-BENZOXAZINES

被引：7

作者：

Masesane, Ishmael B. ^{[1
]}

Muriithi, Eva ^{[1
]}

Tabane, Tebogo H. ^{[1
]}

机构：

[1] Univ Botswana, Dept Chem, Gaborone, Botswana

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA | 2014年 / 28卷 / 02期

关键词：

2-Aminobenzyl alcohol; Benzaldehyde; Acetic acid; 3,1-Benzoxazines; BENZOXAZINE; 4H-3,1-BENZOXAZIN-4-ONES; MECHANOCHEMISTRY; ALDEHYDES; SERIES; ACID;

D O I：

10.4314/bcse.v28i2.14

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The grinding-induced reactions of 2-aminobenzyl alcohol and benzaldehyde derivatives in the presence of 30 mol% of acetic acid to give 3,1-benzoxazines are described. The reactions were performed at room temperature affording 3,1-benzoxazines in yields above 95% and high purity when benzaldehyde and its chloro and nitro derivatives were used.

引用

页码：301 / 304

页数：4