Effects of SO42-, NO3- and Cl- ions on crystalline of ZnS and CdS nanoparticles

被引:0
|
作者
Li Qihou [1 ]
Bi Dandan [1 ]
Liu Zhihong [1 ]
Zhang Duomo [1 ]
机构
[1] Cent S Univ, Sch Met Sci & Engn, Changsha 410083, Peoples R China
关键词
CdS; ZnS; crytallity; wurtzite-type; blende-type;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Mono-disperse ZnS and CdS nano-particles were prepared by the homogenous precipitation method and the effects of SO42-,NO3- and Cl- ions on crystalline of particles were investigated experimentally. The results showed that these anions had no influence on the crystalline of ZnS, but different crystalline CdS ultrafine particles were produced in different anion systems, where the blend-type CdS was obtained from natrate or sulphate solution, and wurtzite-type CdS from chloride solution. It was ascribed to the coordination of Cl- and Cd2+ that altered the supersaturation of precipitate ions in the solution, the existing growth units and their connecting patterns, thereby producing wurtzite-type CdS with a more stable structure.
引用
收藏
页码:129 / +
页数:3
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