Highly efficient bio-sorption of trivalent f-elements using wild type Rhizopus arrhizus dead fungus

被引：11

作者：

Kishor, Preetam ^{[1
]}

Sengupta, Arijit ^{[2
]}

Adya, V. C. ^{[2
]}

Salvi, N. A. ^{[3
]}

机构：

[1] Visva Bharati, Integrated Sci Educ & Res Ctr, Santini Ketan, W Bengal, India

[2] Bhabha Atom Res Ctr, Radiochem Div, Bombay, Maharashtra, India

[3] Bhabha Atom Res Ctr, Bioorgan Div, Bombay, Maharashtra, India

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2017年 / 312卷 / 02期

关键词：

Bio-sorption; Rhizopus arrhizus; Isotherm; Luminescence; Kinetics; MINOR ACTINIDES; SOLVENT-EXTRACTION; IONIC LIQUID; BIOSORPTION; COMPLEXATION; URANIUM; EU3+; LUMINESCENCE; ADSORPTION; BEHAVIOR;

D O I：

10.1007/s10967-017-5214-1

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Wild type Rhizopus arrhizus biomass was demonstrated as highly efficient bio-sorbent for trivalent f-elements. Both Am3+ and Eu3+ were found to follow the Fruendlich isotherm through chemi-sorption. The sorption for Am3+ was found be faster compared to Eu3+ while both proceeded via pseudo-second order reaction. EDTA was found to be effective strippant whereas up to 500 kGy, the bio-sorbent showed high radiolytic stability. Luminescence employed for probing the local environment of metal ion on sorption which revealed the presence of single adsorbed species with no inner sphere water molecules. The covalency of metal-ligand bond enhanced on complexation with the bio-sorbent.

引用

页码：395 / 403

页数：9

共 3 条

[1] Highly efficient bio-sorption of trivalent f-elements using wild type Rhizopus arrhizus dead fungus
Preetam Kishor
Arijit Sengupta
V. C. Adya
N. A. Salvi
Journal of Radioanalytical and Nuclear Chemistry, 2017, 312 : 395 - 403
[2] Highly efficient binding of trivalent f-elements from acidic media with a C3-symmetric tripodal ligand containing diglycolamide arms
Matloka, K
Gelis, A
Regalbuto, M
Vandegrift, G
Scott, MJ
DALTON TRANSACTIONS, 2005, (23) : 3719 - 3721
[3] Poly(amidoamine) Dendrimer Functionalized Carbon Nanotube for Efficient Sorption of Trivalent f-Elements: A Comparison Between 1st And 2nd Generation
Kumar, Parveen
Sengupta, Arijit
Deb, Ashish Kumar Singha
Ali, Sk. Musharaf
CHEMISTRYSELECT, 2017, 2 (03): : 975 - 985

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